Roman noblewoman's tomb reveals secrets of ancient concrete resilience
Study shows how changing chemistry in Roman mortar strengthens the tomb
over time

Date:
October 8, 2021
Source:
University of Utah
Summary:
Over time, concrete cracks and crumbles. Well, most concrete cracks
and crumbles. Structures built in ancient Rome are still standing,
exhibiting remarkable durability despite conditions that would
devastate modern concrete. One of these structures is the large
cylindrical tomb of first- century noblewoman Caecilia Metella. New
research shows that the quality of the concrete of her tomb may
exceed that of her male contemporaries' monuments because of the
volcanic aggregate the builders chose and the unusual chemical
interactions with rain and groundwater with that aggregate over
two millennia.



FULL STORY ==========================================================================
Over time, concrete cracks and crumbles. Well, mostconcrete cracks
and crumbles. Structures built in ancient Rome are still standing,
exhibiting remarkable durability despite conditions that would devastate
modern concrete.


==========================================================================
One of these structures is the large cylindrical tomb of first-century noblewoman Caecilia Metella. New research shows that the quality of
the concrete of her tomb may exceed that of her male contemporaries'
monuments because of the volcanic aggregate the builders chose and
the unusual chemical interactions with rain and groundwater with that
aggregate over two millennia.

"The construction of this very innovative and robust monument and
landmark on the Via Appia Antica indicates that she was held in high
respect," says Marie Jackson, research associate professor of geology
and geophysics at the University of Utah, "and the concrete fabric 2,050
years later reflects a strong and resilient presence." The research is published in the Journal of the American Ceramic Society and is funded
in part by the U.S. Department of Energy ARPA-e "Extreme Durability of Cementitious Materials" program.

Who was Caecilia Metella? The tomb of Caecilia Metella is a landmark
on the Via Appia Antica, an ancient Roman road also known as the Appian
Way. It consists of a drum-shaped tower that sits on a square base, in
total about 70 feet (21 m) tall and 100 feet (29 m) in diameter. Built
about 30 BCE, at the transformation of the Roman Republic to the Roman
Empire, led by Emperor Augustus, in 27 BCE, the tomb is considered one
of the best-preserved monuments on the Appian Way (a castle attached to
the tomb was built in the 14th century).



========================================================================== Caecilia herself was a member of a wealthy family, the daughter of a
Roman consul. She married into the family of Marcus Lincius Crassus,
a Roman general and statesman who formed a famous triumvirate alliance
with Julius Caesar and Pompey.

Not much more is known about Caecilia's life, but the enduring magnitude
of her tomb has caught the attention of visitors for centuries, including
Lord Byron who wrote of the tomb in "Childe Harold's Pilgrimage" in the
early 1800s. After describing the fortress-like structure, Byron asks:
"What was this tower of strength? within its cave What treasure lay so
lock'd, so hid? -- A woman's grave." Jackson visited the tomb in 2006
with archaeologist Dottoressa Lisa Gianmichele and with a permit from
the Soprintendenza Archeologia di Roma to collect small samples of the
mortar for analysis.



==========================================================================
"It was a very warm day in June," she says, "yet when we descended the
steps to the sepulchral corridor the air became very cool and moist." She
notes the compact, cohesive, nearly perfectly preserved brick masonry
walls and the nearly water-saturated volcanic rock outcrop in the sub-structure.

"The atmosphere was very tranquil," she adds, "except for the fluttering
of pigeons in the open center of the circular structure." What is
Roman concrete? Before diving into the particulars, let's get oriented
to the terminology of concrete. Walk along most any sidewalk and you'll
see that concrete is made of an aggregate (rock sands and gravels) and a
cement binder. The cement in a modern sidewalk is likely Portland cement, produced by heating limestone and clay minerals in a kiln to form clinker, grinding the clinker and adding a small amount of gypsum.

The tomb is an example of the refined technologies of concrete
construction in late Republican Rome that contain no cement. The
technologies were described by the architect Vitruvius during the period
when the tomb of Caecilia Metella was under construction. Building thick
walls of coarse brick or volcanic rock aggregate bound with mortar made
with hydrated lime and volcanic tephra (porous fragments of glass and
crystals from explosive eruptions), would result in structures that
"over a long passage of time do not fall into ruins." Vitruvius' words
are proven true by the many Roman structures standing today, including
Markets of Trajan (built between 100 and 110 CE, more than a century
after the tomb) and marine structures like piers and breakwaters, which
Jackson and her colleagues have also studied.

What the ancient Romans couldn't have known, though, is how crystals of
the mineral leucite, which is rich in potassium, in the volcanic tephra aggregate would dissolve over time to beneficially remodel and reorganize
the cohesion of the concrete.

To understand the mineral structure of the concrete, Jackson teamed up
with researchers Linda Seymour and Admir Masic from the Massachusetts
Institute of Technology and Nobumichi Tamura at the Lawrence Berkeley
National Laboratory.

They delved into the microstructure of the concrete with an array of
powerful scientific tools.

"Samples such as ancient mortar are highly heterogeneous and complex, made
of a mixture of different crystalline phases with grain sizes ranging from
a few micrometers down to a few nanometers," says Tamura, who conducted analyses using the Advanced Light Source beamline 12.3.2. To identify
the different minerals in the sample, as well as their orientation, he
says, you need an instrument like the microdiffraction beamline at the
Advanced Light Source that produces a "micron size, extremely bright
and energetic pencil X-ray beam that can penetrate through the entire
thickness of the samples, making it a perfect tool for such a study."
Seymour, who participated in this study as a Ph.D. student at MIT and
is now a project consultant with engineering firm Simpson, Gumpertz &
Heger, conducted additional analyses on the samples.

"Each of the tools that we used added a clue to the processes
in the mortar," she says. Scanning electron microscopy showed
the micro-structures of mortar building blocks at the micron
scale. Energy-dispersive X-ray spectrometry showed the elements comprising
each of those building blocks. "This information allows us to explore
different areas in the mortar quickly, and we could pick out building
blocks related to our questions," she says. The trick, she adds, is to precisely hit the same building block target with each instrument when
that target is only about the width of a hair.

Why is the concrete at Caecilia's tomb so unique? In the thick concrete
walls of Caecilia Metella's tomb, a mortar that contains volcanic tephra
from the nearby Pozzolane Rosse pyroclastic flow (a dense mass of hot
tephra and gases ejected explosively from the nearby Alban Hills volcano)
binds large chunks of brick and lava aggregate. It is much the same
mortar used in the walls of the Markets of Trajan 120 years later.

In previous analysis of the Markets of Trajan mortar, Jackson, Tamura
and their colleagues explored the "glue" of the mortar, a building block
called the C-A- S-H binding phase (calcium-aluminum-silicate-hydrate),
along with a mineral called stra"tlingite. The stra"tlingite crystals
block the propagation of microcracks in the mortar, preventing them from linking together and fracturing the concrete structure.

But the tephra the Romans used for the Caecilia Metella mortar was more abundant in potassium-rich leucite. Centuries of rainwater and groundwater percolating through the tomb's walls dissolved the leucite and released
the potassium into the mortar. In modern concrete, such a flood of
potassium would create expansive gels that would cause microcracking
and eventual spalling and deterioration of the structure.

In the tomb, however, the potassium dissolved and reconfigured the
C-A-S- H binding phase. Seymour says that X-ray microdiffraction and
Raman spectroscopy techniques allowed them to explore how the mortar had changed. "We saw C-A-S-H domains that were intact after 2,050 years and
some that were splitting, wispy or otherwise different in morphology,"
she says. X-ray microdiffraction, in particular, allowed an analysis
of the wispy domains down to their atomic structure. "We see that the
wispy domains are taking on a nano- crystalline nature," she says.

The remodeled domains "evidently create robust components of cohesion in
the concrete," says Jackson. In these structures, unlike in the Markets
of Trajan, there's much less stra"tlingite formed.

Stefano Roascio, the archaeologist in charge of the tomb, notes that
the study has a great deal of relevance to understanding other ancient
and historic concrete structures that use Pozzolane Rosse aggregate.

Admir Masic, associate professor of civil and environmental engineering
at MIT, says that the interface between the aggregates and the mortar
of any concrete is fundamental to the structure's durability. In modern concrete, he says, the alkali-silica reactions that form expansive gels
may compromise the interfaces of even the most hardened concrete.

"It turns out that the interfacial zones in the ancient Roman concrete of
the tomb of Caecilia Metella are constantly evolving through long-term remodeling," he says. "These remodeling processes reinforce interfacial
zones and potentially contribute to improved mechanical performance
and resistance to failure of the ancient material." Can we recreate
that effect today? Jackson and her colleagues are working to replicate
some of the Romans' successes in modern concretes, specifically in a
U.S. Department of Energy ARPA-e project to encourage similar beneficially reactive aggregates in concretes that use engineered cellular magmatics
in place of the tephra of the ancient Roman structures. The objective, according to ARPA-e, is that a Roman- like concrete could reduce the
energy emissions of concrete production and installation by 85% and
improve the 50-year lifespan of modern marine concretes four-fold.

"Focusing on designing modern concretes with constantly reinforcing
interfacial zones might provide us with yet another strategy
to improve the durability of modern construction materials,"
Masic says. "Doing this through the integration of time-proven
'Roman wisdom' provides a sustainable strategy that could improve
the longevity of our modern solutions by orders of magnitude." ========================================================================== Story Source: Materials provided by University_of_Utah. Original written
by Paul Gabrielsen.

Note: Content may be edited for style and length.


========================================================================== Related Multimedia:
* Roman_noblewoman's_tomb.

========================================================================== Journal Reference:
1. Linda M. Seymour, Nobumichi Tamura, Marie D. Jackson, Admir Masic.

Reactive binder and aggregate interfacial zones in the mortar of
Tomb of Caecilia Metella concrete, 1C BCE, Rome. Journal of the
American Ceramic Society, 2021; DOI: 10.1111/jace.18133 ==========================================================================

Link to news story: https://www.sciencedaily.com/releases/2021/10/211008134107.htm

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