Research pushes auto industry closer to clean cars powered by direct
ethanol fuel cells

Date:
November 29, 2021
Source:
Oregon State University
Summary:
Alternative-energy research is charting a path toward the mass
adoption of clean cars powered by direct-ethanol fuel cells.



FULL STORY ========================================================================== Alternative-energy research at Oregon State University is charting a
path toward the mass adoption of clean cars powered by direct-ethanol
fuel cells.


========================================================================== Zhenxing Feng of the OSU College of Engineering helped lead the
development of a catalyst that solves three key problems long associated
with DEFC, as the cells are known: low efficiency, the cost of catalytic materials and the toxicity of chemical reactions inside the cells.

Feng and collaborators at Oregon State, the University of Central Florida
and the University of Pittsburgh found that putting fluorine atoms into palladium- nitrogen-carbon catalysts had a number of positive effects -- including keeping the power-dense cells stable for nearly 6,000 hours. A catalyst is a substance that increases the rate of a reaction without
itself undergoing any permanent chemical change.

Findings were published today in Nature Energy.

Cars and trucks powered by gasoline or diesel engines rely on the
combustion of fossil fuels, which results in emissions of the greenhouse
gas carbon dioxide.

Motor vehicles are one of the main sources of atmospheric CO2, a primary
factor in climate change.

"Combustion engines produce enormous amounts of carbon dioxide,"
said Feng, associate professor of chemical engineering. "To achieve carbon-neutral and zero-carbon-emissions goals, alternative energy
conversion devices using the fuel from renewable and sustainable sources
are urgently needed. Direct-ethanol fuel cells can potentially replace gasoline- and diesel-based energy conversion systems as power sources."
Feng and collaborators are in the process of soliciting funding to
develop prototypes of DEFC units for portable devices and vehicles.



==========================================================================
"If this is successful, we can deliver a device for commercialization
in five years," he said. "With more industrial collaborators, the DEFC
vehicle can be implemented in 10 years, hopefully." Ethanol, also known
as ethyl alcohol, consists of carbon, hydrogen and oxygen - - its chemical formula is C2H6O -- and is the active ingredient in alcoholic drinks. It
occurs naturally through the fermentation of sugars by yeasts and can be derived from many sources including corn, wheat, grain sorghum, barley,
sugar cane and sweet sorghum.

Most of the ethanol produced in the United States is made in the Midwest,
most typically from corn.

A fuel cell, Feng explains, relies on the chemical energy of hydrogen
or other fuels to cleanly and efficiently produce electricity. They can
use a wide range of fuels and feedstocks and can serve systems as large
as a utility power plant and as small as a laptop computer.

"In DEFC technology, ethanol can be generated from a number of sources, particularly biomass like sugar cane, wheat and corn," Feng said. "The
benefit of using biological sources to produce ethanol is that plants
absorb atmospheric carbon dioxide." A liquid and thus easily stored and transported, ethanol can deliver more energy per kilogram than other fuels
like methanol or pure hydrogen. Plus, Feng points out, infrastructure
is already in place for both producing and distributing ethanol, making
DEFC an attractive option for replacing internal combustion engines.



==========================================================================
"The first vehicle powered by an ethanol-based fuel cell was developed
in 2007," Feng said. "However, the further development of DEFC vehicles
has significantly lagged due to the low efficiency of DEFC, the costs
related to catalysts and the risk of catalyst poisoning from carbon
monoxide produced in reactions inside the fuel cell." To tackle those
problems the research team, which also included OSU's Maoyu Wang and
scientists from Southern University of Science and Technology in China
and Argonne National Laboratory, developed high-performance palladium
alloy catalysts that use less of the precious metal than current palladium-based catalysts.

Palladium, platinum and ruthenium are elements valued for their catalytic properties but expensive and difficult to obtain.

"Our team showed that introducing fluorine atoms into
palladium-nitrogen-carbon catalysts modifies the environment around
the palladium, and that improves both activity and durability for two
important reactions in the cell: the ethanol oxidation reaction and
the oxygen reduction reaction," Feng said. "Advanced synchrotron X-ray spectroscopy characterizations made at Argonne suggest that fluorine atom introduction creates a more nitrogen-rich palladium surface, which is
favorable for catalysis. Durability is enhanced by inhibiting palladium migration and decreasing carbon corrosion." Supporting this research
were the National Science Foundation and the U.S.

Department of Energy.

========================================================================== Story Source: Materials provided by Oregon_State_University. Original
written by Steve Lundeberg. Note: Content may be edited for style
and length.


========================================================================== Journal Reference:
1. Jinfa Chang, Guanzhi Wang, Maoyu Wang, Qi Wang, Boyang Li, Hua Zhou,
Yuanmin Zhu, Wei Zhang, Mahmoud Omer, Nina Orlovskaya, Qing Ma, Meng
Gu, Zhenxing Feng, Guofeng Wang, Yang Yang. Improving Pd-N-C fuel
cell electrocatalysts through fluorination-driven rearrangements
of local coordination environment. Nature Energy, 2021; DOI:
10.1038/s41560-021- 00940-4 ==========================================================================

Link to news story: https://www.sciencedaily.com/releases/2021/11/211129122813.htm

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