New ice is like a snapshot of liquid water

Date:
February 2, 2023
Source:
University of Cambridge
Summary:
Scientists have discovered a new form of ice that more closely
resembles liquid water than any other and may hold the key to
understanding this most famous of liquids.


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FULL STORY ==========================================================================
A collaboration between scientists at Cambridge and UCL has led to the discovery of a new form of ice that more closely resembles liquid water
than any other and may hold the key to understanding this most famous
of liquids.


==========================================================================
The new form of ice is amorphous. Unlike ordinary crystalline ice where
the molecules arrange themselves in a regular pattern, in amorphous ice
the molecules are in a disorganised form that resembles a liquid.

In this paper, published in Science, the team created a new form of
amorphous ice in experiment and achieved an atomic-scale model of it in computer simulation. The experiments used a technique called ball-milling, which grinds crystalline ice into small particles using metal balls in a
steel jar. Ball- milling is regularly used to make amorphous materials,
but it had never been applied to ice.

The team found that ball-milling created a novel amorphous form of ice,
which unlike all other known ices, had a density similar to that of
liquid water and whose state resembled water in solid form. They named
the new ice medium- density amorphous ice (MDA).

To understand the process at the molecular scale the team employed computational simulation. By mimicking the ball-milling procedure via
repeated random shearing of crystalline ice, the team successfully
created a computational model of MDA.

"Our discovery of MDA raises many questions on the very nature of
liquid water and so understanding MDA's precise atomic structure is very important" comments co-author Dr. Michael Davies, who carried out the computational modelling. "We found remarkable similarities between MDA
and liquid water." A happy medium Amorphous ices have been suggested
to be models for liquid water. Until now, there have been two main types
of amorphous ice: high-density and low-density amorphous ice.

As the names suggest, there is a large density gap between them. This
density gap, combined with the fact that the density of liquid water lies
in the middle, has been a cornerstone of our understanding of liquid
water. It has led in part to the suggestion that water consists of two
liquids: one high- and one low-density liquid.

Senior author Professor Christoph Salzmann said: "The accepted wisdom has
been that no ice exists within that density gap. Our study shows that the density of MDA is precisely within this density gap and this finding may
have far-reaching consequences for our understanding of liquid water and
its many anomalies." A high-energy geophysical material The discovery
of MDA gives rise to the question: where might it exist in nature? Shear
forces were discovered to be key to creating MDA in this study.

The team suggests ordinary ice could undergo similar shear forces in the
ice moons due to the tidal forces exerted by gas giants such as Jupiter.

Moreover, MDA displays one remarkable property that is not found
in other forms of ice. Using calorimetry, they found that when MDA recrystallises to ordinary ice it releases an extraordinary amount of
heat. The heat released from the recrystallization of MDA could play a
role in activating tectonic motions. More broadly, this discovery shows
water can be a high-energy geophysical material.

Prof. Angelos Michaelides, lead author from Cambridge, said: "Amorphous
ice in general is said to be the most abundant form of water in the
universe. The race is now on to understand how much of it is MDA and
how geophysically active MDA is."
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========================================================================== Story Source: Materials provided by University_of_Cambridge. The original
text of this story is licensed under a Creative_Commons_License. Note:
Content may be edited for style and length.


========================================================================== Journal Reference:
1. Alexander Rosu-Finsen, Michael B. Davies, Alfred Amon, Han Wu,
Andrea
Sella, Angelos Michaelides, Christoph G. Salzmann. Medium-density
amorphous ice. Science, 2023; 379 (6631): 474 DOI: 10.1126/
science.abq2105 ==========================================================================

Link to news story: https://www.sciencedaily.com/releases/2023/02/230202153559.htm

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